Photopolymerizing composition

专利摘要:

公开号:SU948300A3
申请号:SU782702501
申请日:1978-12-21
公开日:1982-07-30
发明作者:Фельдер Люис；Кирхмайр Рудольф；ХЮСЛЕР Ринальдо
申请人:Циба-Гейги Аг (Фирма)；
IPC主号:

专利说明:

one
The invention relates to photo-extensible compositions that can be used in photolithographic processes, for example, in microelectronics, as well as in the manufacture of UV-curable printing inks in printing.
A photopolymer is known with a Cl composition comprising a film-forming component and a photoinitiator, which is a mixture of benzoyl esters of the formula

CeHjdcfHdeHs II
where R is a
alkoxy.
The disadvantage of this composition The disadvantage is that it has unsatisfactorily low photosensitivity and low storage stability.
The purpose of the invention is to increase the sensitivity and stability of the composition during storage in Themota.
The goal is achieved by the fact that photo-polymerization with coklozitsi, including film-forming component and photoinitiator, as
ve photoinitiator contains a compound of the general formula
R
kg and rt
ChS-l
I .I Jn
(i)
Rl
1 or 2;
Where
S C -Ct-alkyl or
- ij -Vj / -allil ilp
СНпСНоСОО-С -С4-АЛЬКИЛ}
R-like Ri or together with K C.-Cc-alkylene,
-fennl, tetrahydronaphthyl or mono- or disubstituted chlorine, bromine Cj-C-alkyl
C-SL-alkylC-Cd-alkoxy,
thio, phenoxy, if p-1, and R - phenylene-O-phenylene or phenylene-5-phenylene, if p-2: X -,
R and R | - C-C-alkyl or R and i R together with the nitrogen atom form a piperidine or morpholine ring J R - hydrogen, C-C-alkyl,
Ca-C - alkoxyalkyl, Cj-Cj-alkenyl
and additionally cross-linking; di- or triacrylate in the following ratio of components, parts by weight:
Film-forming component. 55-90 Di- or triacrylate10-30
Photoinitiator specified formula0, 5-10
In order to obtain marginal images, the composition may additionally contain 20 parts by weight. pigmen and / or 0.5 weight.h. in advance of the yugtel conducive to spill.
As photoinitiators of the formula I, compounds can be used whose structural forms and physical properties are listed in Table. one.
Example 1. Films with a thickness of 40 microns from a mixture of resins consisting of 80 h. Plex 6616 (acrylate resin from Rohm, Darmstadt), 20 h. Trimethylpropane-triacrylate, and 2 h. photoinitiator. The films are blown over about 20 with air and then irradiated under a medium-pressure mercury lamp (Hanovia, device 45080). In this case, the samples are mixed under the ultraviolet lamp on the conveyor belt at such a rate that the effective irradiation time in one pass was 0.16 s.
In tab. Table 2 shows the number of CR passes required for obtaining solid, non-adhesive films, the hardness of the films after different number of passes measured by Koenig with a mapping instrument, and also shows the stability of the mixture of resin with photoinitiator when stored in the dark at.
Example 2. 30 micron thick films of resin mixture consisting of 60 hours Uvimcr DV-530 (Polychrom urethane acrylate), 3 hours, hexanediol diacrylate and 3 parts of photoinitiator were applied to glass plates. The film illuminated in the same way as in example 1. The results are shown in table. 3
Example 3.2% of the photoinitiator is dissolved in an unsaturated polyester resin (Crystic PKE 306, Maeder, Killwangen, Switzerland). This mixture is applied on glass plates in the form of films with a thickness of 60 microns, which then are illuminated in the same way as in Example 1. Table B. Figure 4 shows data on the number of passes of the plates through the device for irradiation, the necessary DZT for obtaining films that are resistant to abrasion, as well as on the hardness of a parallel device, depending on the number of passes.
Example 4. A mixture of resins consisting of 90 parts. Zaromer ZR 8496 (acrylate grade BASF, Germany), 10 hours hexanediol diacrylate / 0.5 hours. WoK 300 (demolishing agent, HyK-Mallinckrodt, Germany) and 3 Photoinitiator for curing in air, respectively, 0.5 hours. Photoinitiator for curing in nitrogen atmosphere, using a 15 / x thick spiral motor, are applied to pieces of cardboard. After a brief exposure to air, the rejection was carried out using an ultraviolet device (model PPG / Q, C-processor) with an 80 V / cm ultraviolet lamp. In tab. Figure 5 shows the maximum transport speeds in m / min at which non-adhesive films are produced in an atmosphere of air or nitrogen.
Example 5. A layer of resin mixture 30-40 microns thick consisting of 70 h. Eeryery1 (polyester acrylate from ISV, Belgium), 30 h. Trimethylol propane tri-crylate, 0.5 h. WoK ( a means of promoting the spill, the company ByK-Mallinckrodt, Germany) and, 3 hours photoinitiator. After a short exposure to air, they are cured with an ultraviolet device (model PPG / Q, C-processor) with an 80 W / cm ultraviolet lamp. After curing, the plate is held for half an hour.
5 under normal climatic conditions, and then hardness is determined by a math instrument according to Koenig. Table 6 shows the measured values of hardness as a function of speed
0 transporting plates under the lamp.
Example 6. Blue printing ink was prepared as follows. Take 55 weight.h. Setalina AR 560
5 (Setalin - acrylate resin company Synthese, Holland), 17 weight.h. 4,4-di (p-acryloyloxyethoxy) -diphenyl-propane-2, 2 (Ebecryl 150), 20 parts by weight Ingalith GLSM (blue pig (menT from Ciba Geigy, Basel), 4 parts by weight of N-methyl-diethanolamine and 4 parts by weight of 8 o compound) as photoinitiator.
First, Setalin and Irgalith are ground in a ball mill to obtain a thick-rubbed paint. N-methyl-diethanolamine and photoinitiator rast-. they steal into Ebecryl and homogenize with a thick paint in a disc grater.
The printing ink thus obtained is filled with a special paper bag using a test printed 5 set. Prerequisites: Printing ink, Stuffed pressure, kgf / m 25 Packing speed, m / s2 Samples are irradiated with UV rays (lamp power 80 W / cm, distance from the lamp 11 cm), irradiation time varies by changing the speed of sample transport. Drying of the surface is determined by friction, wadding vMaH to a sample of white paper under pressure Compound
The physical properties are 25 kgf / cm2. If the paper remains white, the result is considered positive, which is the case for all samples irradiated at a transport speed of 75 m / min. When using benzoin isobutyl ether as a photoinitiator (according to the prototype), the maximum transport speed is no more than 15 m / min. The printing ink with the compound is retained in the dark without deteriorating its properties for at least 30 days, and the ink with benzoin isopropyl ester is gelatin and disinfects for one day. Table 1 IX
kroa b t kip.
0-no.
Kpftno 110-112 78-80 °
Kpg 120 ° T. Kip.
Oil nista liquid
150
Cro, 1 t, kip.
CROI °
bp
KRO ,. 130 bp
 about SNS
 e-1-he.
Cr ,,, 130 t.kip.
 f- II I T.
five
 Vd --- | OH waxed
HO-Mii
SNS
Continued table. one
T. Kip.
Bp ISQ
about IT / product
toj
about dHs
18
yn
dH oh
1 5 II
M.p. 141-143 °
ciH.3
YNZ
n, e hjd
Continued table. one
Is he
t.kip
i
e- | - /))
T, pl. 110-112 enz
M.p. 34 T.K. 150
T. Kip. 150
T, W1. 68-71 bp. 210 °
Oil nista liquid
Oil nista liquid
Oil nista liquid
Oil nista liquid
T.sh. 38-41 2-Phenyl-di-methoxy112 (b) -acetophenone (comparison) b P-Methyl-oL / oL-dimorpholinoacetophenone (comparison) 8 92. (8) oL / o1-Dimorfolino84 (17) acetophenone (comparison) 17
Photoinitiator
12
Diethoxyg.tetophone (comparison)
Benzoin tert-butyl ester (prototype)
2-phenyldimethoxy acetophenone (comparison)
T a b L and c a
3D
 5 -1 1
Table 3
Kanig trough hardness versus number of passes (D)
129 (3)
157 (3)
156 (10)
136 (12)
155 (8) 121 (8) 130 (10) 100 (10) 109 (12) 98 (19)
Table 5 Table b
Table 4

权利要求:
Claims (2)
[1]
Continued table. B 5Q gg. Formula 1: Photopolymerizable composition, comprising a film-forming component and a photoinitiator, characterized in that, in order to increase the photosensitivity and stability of the composition during storage in the dark, as a photoinitiator, it contains a compound of total forglyla O: R i ffc-V L 4yy -J / 7 where n is 1 or 2; R is phenyl, tetrahydronaphthyl, or MONO-, or disubstituted with chlorine, bromine C, -C4-alkl, C) -C-alkoxy, C-C-alkylthio, phenoxy, if h-1, R3 is phenyler-O -phenylene and phenylene-5-phenylene, if X -, OR R - (, -alkyl or CH, CHaCOO-C-C4-alkyl gi - as R or together with R C4-C5-alkylene / „R and R5 - C ., - C4-apkyl or RR together with the nitrogen atom form a piperidine or morpholine ring} R - hydrogen chloride, C; - C (, - alkyl, C-alkoxyalkyl, SuS-alkene and additionally donating agent di or triacrylate with the following ratio of boilers , weight.h .: Film-forming co1 “1 dent Dy- 0LI three krillat Photo initiator the odd form--, -, o: 5th muly
[2]
2. Composition pr P. 1, about tl and h aa ad q - T6W7 4Tt) ;, With ijc i iettH “-colored images, it additionally contains 20 pigment weight and / nli 0.5. auxiliary agents that assist in the spill. 16 according to the signs: with R -, - alkyl or CH, 2 CHg COO-C-1-C4-alkyl; R - as R or together with R - Cd-Su-alkylene / R-phenyl or mono- or disubstituted with chlorine, bromine. -Sylkyl, -scKOXY, C-C -s1-LKILthio, if n-1, and R phenylene-O -phenylene or phenyl-5-Leninene, if p-2, X -, R and R are C -C-alkyl or R and R together with the nitrogen atom form a piperidine or morpholine ring, R is hydrogen or (j-alkyl, C -C-alkoxyalkyl, C5-C5-alkenyl, with R - substituted phenoxy-prn R - tetrahydronaphthyl, if n-1. Infozhiatsii sites, attention Dry-Expertise of the Federal Republic of Germany 2107934, 4, published 1971.

类似技术:

---

公开号 | 公开日 | 专利标题

---

SU948300A3|1982-07-30|Photopolymerizing composition

---

AU613980B2|1991-08-15|Radiation-polymerizable acrylate and alkacrylate compounds

---

AU603196B2|1990-11-08|Polymerizable N-containing acrylates and a radiation-polymerizable mixture containing same

---

US3933682A|1976-01-20|Photopolymerization co-initiator systems

---

US4666952A|1987-05-19|Photopolmerizable mixtures containing tertiary amines as photoactivators

---

US4434035A|1984-02-28|Mixtures of aromatic-aliphatic ketones as photoinitiators and photopolymerizable systems containing them

---

CA1105758A|1981-07-28|PHOTOSENSITIVE COMPOSITIONS CONTAINING A COPOLYMER DERIVED FROM A CONJUGATED DIOLEFIN AND AN .alpha. .beta. ETHYLENICALLY UNSATURATED CARBOXYLIC ACID OR ANHYDRIDE

---

CA1094744A|1981-01-27|Photosensitizers for radiation-curable coatins

---

US3966573A|1976-06-29|Photopolymerization co-initiator systems

---

US4264483A|1981-04-28|Decorating ink

---

US5645974A|1997-07-08|Process for the production of printing plates

---

AU610962B2|1991-05-30|Photopolymerizable mixture, and a recording material produced therefrom

---

CA1050696A|1979-03-13|Radiation curable acrylic and methacrylic esters of diethanolamines

---

US6316552B1|2001-11-13|Diacrylates and dimethacrylates

---

CA1143098A|1983-03-15|Radiation curable michael addition amine adductsof amide acrylate compounds

---

US4113593A|1978-09-12|Benzophenone-containing photopolymerizable binders for printing inks and coating compositions

---

US5096935A|1992-03-17|6-acyl-|-dibenz[c,e][1,2]oxaphosphorin 6-oxides, their preparation and their use as photoinitiators

---

GB1602620A|1981-11-11|Photopolymerizable composition for the manufacture of printing plates and relief plates

---

GB2106112A|1983-04-07|A glycol monoacrylate or diacrylate and a composition containing the diacrylate

---

JPH0641213A|1994-02-15|Method of obtaining texture coating film from photocurable urea-containing composition

---

US4985341A|1991-01-15|Photopolymerizable mixture, and a recording material produced therefrom

---

US4224399A|1980-09-23|Photocrosslinkable compositions for lithographic printing plates

---

US4188224A|1980-02-12|Photopolymerizable composition containing anthrones

---

CA1088057A|1980-10-21|Light-sensitive copying compositions and photoinitiators contained therein

---

GB1490428A|1977-11-02|Radiation curable decorating inks

同族专利:

---

公开号 | 公开日

---

US4308400A|1981-12-29|

---

FI64169C|1983-10-10|

---

JPH0248536B2|1990-10-25|

---

JPH01139554A|1989-06-01|

---

DK157083C|1990-03-19|

---

US4321118A|1982-03-23|

---

GR71655B|1983-06-20|

---

ATA917678A|1982-05-15|

---

JPH0257081B2|1990-12-04|

---

BR7808406A|1980-05-20|

---

US4315807A|1982-02-16|

---

US4318791A|1982-03-09|

---

DD141320A5|1980-04-23|

---

AR226169A1|1982-06-15|

---

EP0003002B1|1984-06-13|

---

AU4277578A|1979-06-28|

---

EP0003002A2|1979-07-11|

---

HU181680B|1983-11-28|

---

AT369392B|1982-12-27|

---

AU529495B2|1983-06-09|

---

FI64169B|1983-06-30|

---

EP0003002A3|1980-01-09|

---

DK576278A|1979-06-23|

---

JPH01308404A|1989-12-13|

---

PL117576B1|1981-08-31|

---

FI783919A|1979-06-23|

---

JPS5499185A|1979-08-04|

---

DK157083B|1989-11-06|

---

PL212042A1|1979-09-10|

---

JPH0134242B2|1989-07-18|

---

CA1234242A|1988-03-15|

引用文献:

---

公开号 | 申请日 | 公开日 | 申请人 | 专利标题

---

---

DE651543C|1936-03-21|1937-10-16|Chemische Werke Vorm H & E Alb|Process for the preparation of ªÏ-dimethylaminoalkylaryl ketones|

---

DE671786C|1937-11-16|1939-02-13|Albert Ag Chem Werke|Process for the preparation of N - [ methyl] tetrahydro-p-oxazine|

---

US2588123A|1946-11-13|1952-03-04|Gen Electric|Preparation of vinyltetrahydronaphthalenes|

---

US2722512A|1952-10-23|1955-11-01|Du Pont|Photopolymerization process|

---

BE565446A|1957-03-06|

---

CH365381A|1957-03-29|1962-11-15|Morren Henri|Process for the preparation of piperazine derivatives|

---

NL128358C|1958-12-19|

---

DE1164388B|1959-03-02|1964-03-05|Temmler Werke|Process and apparatus for the production of aryl alkyl bromoketones|

---

US3465039A|1962-09-17|1969-09-02|Andreas J Rottendorf Chem Fab|Therapeutically active secondary and tertiary 1 - halogenphenyl - 2 - amino-alkanones |

---

NL283329A|1961-09-18|

---

US3171858A|1963-08-30|1965-03-02|Parke Davis & Co|alpha-ethylamino-o-methylisobutyrophenone|

---

NL125868C|1964-01-29|

---

DE1694149C2|1967-05-06|1976-01-02|Bayer Ag, 5090 Leverkusen|Polyester molding and coating compounds|

---

DE1769854C3|1968-07-26|1982-08-19|Bayer Ag, 5090 Leverkusen|Photoinitiators and processes for photopolymerization|

---

DE1807301A1|1968-11-06|1970-06-04|Bayer Ag|New butyric acid derivatives|

---

DE1902051A1|1969-01-16|1970-08-13|Bayer Ag|Process for the production of alpha-substituted benzoins and benzoin ethers|

---

US3578682A|1969-03-20|1971-05-11|Ash Stevens Inc|2,5-bis--1,3,4-trithiolanes and process for the preparation thereof|

---

DE1923266B2|1969-05-07|1977-09-29|Basf Ag, 6700 Ludwigshafen|ALPHA-HYDROXYMETHYLBENZOIN ETHER|

---

BE759838A|1969-12-04|1971-06-03|Wellcome Found|KETONES WITH BIOLOGICAL ACTIVITY|

---

US3657088A|1969-12-17|1972-04-18|Bayer Ag|Moulding and coating masses hardenable by uv irradiation|

---

GB1408265A|1971-10-18|1975-10-01|Ici Ltd|Photopolymerisable composition|

---

DE2161085A1|1971-12-09|1973-06-14|Basf Ag|BINDERS FOR LIGHT CURING INKS|

---

US3715293A|1971-12-17|1973-02-06|Union Carbide Corp|Acetophenone-type photosensitizers for radiation curable coatings|

---

DE2232365C2|1972-07-01|1982-06-09|Basf Ag, 6700 Ludwigshafen|Mixtures polymerizable by UV radiation|

---

US3829467A|1972-07-03|1974-08-13|Rorer Inc William H|Tetrahydronaphthylalkanoic acids and their derivatives|

---

NL7315930A|1972-12-06|1974-06-10|

---

US3900478A|1973-01-29|1975-08-19|Squibb & Sons Inc|2-methyl-2-piperidino-3'- propiophenone|

---

JPS5314041B2|1973-03-31|1978-05-15|

---

GB1469643A|1973-11-19|1977-04-06|Ici Ltd|Photopolymerisable composition|

---

US4024324A|1975-07-17|1977-05-17|Uop Inc.|Novel polyolefin composition of matter|

---

US4048038A|1974-07-08|1977-09-13|J. M. Huber Corporation|Electroflocculation cell|

---

US4017652B1|1974-10-23|1986-09-30|

---

US3988228A|1975-08-29|1976-10-26|Eastman Kodak Company|Photopolymerizable polymeric compositions containing halogen containing aromatic ketones|

---

US4040923A|1976-06-03|1977-08-09|Eastman Kodak Company|Photopolymerizable polymeric compositions containing halogen containing aromatic ketones|

---

US4101584A|1976-12-10|1978-07-18|Napp Chemicals Inc.|Bisbenzoin ethers and method of producing benzoin ethers|

---

US4141807A|1977-03-01|1979-02-27|Stauffer Chemical Company|Photopolymerizable composition stabilized with nitrogen-containing aromatic compounds|

---

DE2722264C2|1977-05-17|1984-06-28|Merck Patent Gmbh, 6100 Darmstadt|Use of substituted oxyalkylphenones as photosensitizers|

---

DE2808459A1|1977-05-17|1979-08-30|Merck Patent Gmbh|Substd. hydroxyalkyl-phenone cpds. for use as photosensitisers - esp. in photopolymerisation, and as UV hardeners in printing inks|

---

EP0007468B1|1978-07-13|1982-04-07|Ciba-Geigy Ag|Compositions photodurcissables|

---

US4279720A|1978-07-13|1981-07-21|Ciba-Geigy Corporation|Photocurable composition|DE2722264C2|1977-05-17|1984-06-28|Merck Patent Gmbh, 6100 Darmstadt|Use of substituted oxyalkylphenones as photosensitizers|

---

DE3107087A1|1980-02-29|1981-12-24|CIBA-GEIGY AG, 4002 Basel|"PHOTOPOLYMERIZABLE MIXTURES AND METHOD FOR PHOTOPOLYMERISATION OF CATIONICALLY POLYMERIZABLE COMPOUNDS"|

---

DE3008411A1|1980-03-05|1981-09-10|Merck Patent Gmbh, 6100 Darmstadt|NEW AROMATIC-ALIPHATIC KETONES, THEIR USE AS PHOTOINITIATORS AND PHOTOPOLYMERIZABLE SYSTEMS CONTAINING SUCH KETONES|

---

US4368253A|1981-01-28|1983-01-11|Ciba-Geigy Corporation|Image formation process|

---

DE3203096A1|1982-01-30|1983-08-04|Merck Patent Gmbh, 6100 Darmstadt|USE OF HYDROXYALKYLPHENONES AS INITIATORS FOR THE RADIATION HARDENING OF AQUEOUS PREPOLYMER DISPERSIONS|

---

DE3365773D1|1982-02-26|1986-10-09|Ciba Geigy Ag|Coloured photo-hardenable composition|

---

US4504372A|1982-03-12|1985-03-12|Ciba-Geigy Corporation|Acid-curable composition containing a masked curing catalyst, and a process for its preparation|

---

DE3360384D1|1982-05-07|1985-08-14|Ciba Geigy Ag|Process for the preparation of 1-hydroxyketones|

---

US4498964A|1982-06-15|1985-02-12|Ciba-Geigy Corporation|Process for the photopolymerization of unsaturated compounds|

---

US4518676A|1982-09-18|1985-05-21|Ciba Geigy Corporation|Photopolymerizable compositions containing diaryliodosyl salts|

---

EP0108037B1|1982-10-01|1989-06-07|Ciba-Geigy Ag|Propiophenone derivatives as photoinitiators in the photopolymerization|

---

US4649062A|1983-01-05|1987-03-10|Ciba-Geigy Corporation|Ultraviolet radiation curable vehicle for ceramic colors, composition and method|

---

EP0117233B1|1983-02-18|1987-08-26|Ciba-Geigy Ag|Coloured photo-curable mouldings|

---

US4524221A|1983-02-22|1985-06-18|Minnesota Mining And Manufacturing Company|Process for the production of acyloins|

---

EP0117578A3|1983-02-23|1985-01-30|Shionogi & Co., Ltd.|Azole-substituted alcohol derivatives|

---

US4563438A|1983-05-06|1986-01-07|Ciba Geigy Corporation|Liquid mixture of photoinitiators|

---

US5145885A|1983-08-15|1992-09-08|Ciba-Geigy Corporation|Photopolymerizable compositions containing aminoaryl ketone photoinitiators|

---

DE3471486D1|1983-08-15|1988-06-30|Ciba Geigy Ag|PHOTOCURABLE COMPOSITIONS|

---

US4946874A|1983-10-26|1990-08-07|Dow Corning Corporation|Fast ultraviolet radiation curing silicone composition containing two vinyl polymers|

---

US5124212A|1983-10-26|1992-06-23|Dow Corning Corporation|Articles prepared from fast ultraviolet radiation curing silicone composition|

---

US4780486A|1983-10-26|1988-10-25|Dow Corning Corporation|Fast ultraviolet radiation curing silicone composition|

---

US5169879A|1983-10-26|1992-12-08|Dow Corning Corporation|Fast ultraviolet radiation curing silicone composition|

---

US5162389A|1983-10-26|1992-11-10|Dow Corning Corporation|Fast ultraviolet radiation curing silicone composition having a high refractive index|

---

IT1176018B|1984-04-12|1987-08-12|Lamberti Flli Spa|ALIPHATIC POLYMERIC OR POLYMERIZABLE AROMATIC KETONES SUITABLE FOR USE AS A POLYMERIZATION PHOTO INITIATOR|

---

JPH0450921B2|1984-07-10|1992-08-17|Asahi Denka Kogyo Kk|

---

IT1208494B|1985-01-28|1989-07-10|Lamberti Flli Spa|Polymerization. SULPHURATED DERIVATIVES OF AROMATIC-ALIPHATIC AND ALIPHATIC KETONES AS PHOTOINITIATORS OF|

---

US4666953A|1985-03-28|1987-05-19|Loctite Corporation|Silicone polyphotoinitiators|

---

DE3512179A1|1985-04-03|1986-12-04|Merck Patent Gmbh, 6100 Darmstadt|PHOTO INITIATORS FOR PHOTOPOLYMERIZATION IN AQUEOUS SYSTEMS|

---

FR2583759B1|1985-06-20|1988-01-15|Atochem|PHOTORETICULAR POLYOLEFIN FILMS AND THEIR MANUFACTURING METHOD|

---

US4741981A|1985-07-30|1988-05-03|Ricoh Co., Ltd.|Photosensitive material for electrophotography contains organic phosphite compounds|

---

US4691059A|1985-08-30|1987-09-01|Minnesota Mining And Manufacturing Company|Copolymerizable UV stabilizers|

---

US5529728A|1986-01-28|1996-06-25|Q2100, Inc.|Process for lens curing and coating|

---

US4879318A|1986-01-28|1989-11-07|Ophthalmic Research Group International, Inc.|Plastic lens composition and method for the production thereof|

---

US5364256A|1986-01-28|1994-11-15|Ophthalmic Research Group International, Inc.|Apparatus for the production of plastic lenses|

---

US5415816A|1986-01-28|1995-05-16|Q2100, Inc.|Method for the production of plastic lenses|

---

US6730244B1|1986-01-28|2004-05-04|Q2100, Inc.|Plastic lens and method for the production thereof|

---

US6201037B1|1986-01-28|2001-03-13|Ophthalmic Research Group International, Inc.|Plastic lens composition and method for the production thereof|

---

US4906675A|1986-02-12|1990-03-06|Mitsui Petrochemical Industries, Ltd.|Active energy ray-curable composition|

---

US5288917A|1986-04-15|1994-02-22|Ciba-Geigy Corporation|Liquid photoinitiator mixtures|

---

DE3768919D1|1986-11-26|1991-05-02|Ciba Geigy Ag|Fluessige photoinitiatorgemische.|

---

US5238782A|1986-12-26|1993-08-24|Fuji Photo Film Co., Ltd.|Photopolymerizable composition|

---

AT89262T|1987-03-26|1993-05-15|Ciba Geigy Ag|NEW ALPHA AMINO ACETOPHENONE AS PHOTOINITIATORS.|

---

GB8715435D0|1987-07-01|1987-08-05|Ciba Geigy Ag|Forming images|

---

EP0302831B1|1987-08-05|1993-05-12|Ciba-Geigy Ag|Compounds|

---

US4824875A|1987-11-06|1989-04-25|Dow Corning Corporation|UV curable conformal coating with moisture shadow cure|

---

US4956221A|1987-11-06|1990-09-11|Dow Corning Corporation|UV curable conformal coating with moisture shadow cure|

---

US4791045A|1988-01-25|1988-12-13|Minnesota Mining And Manufacturing Company|Photosensitizers and polymerizable compositions with mannich bases and iodonium salts|

---

FR2626880B1|1988-02-10|1990-06-08|Lafon Labor|N-SUBSTITUTED DERIVATIVES OF 2-AMINO-1-PHENYLPROPANONE, METHOD OF PREPARATION AND THERAPEUTIC USE|

---

DE3816304A1|1988-05-13|1989-11-23|Merck Patent Gmbh|PHOTOINITIATOR COPOLYMERS|

---

DE3826947A1|1988-08-09|1990-02-22|Merck Patent Gmbh|THIOXANTHON DERIVATIVES, THEIR USE AS PHOTOINITIATORS, PHOTOPOLYMERIZABLE BINDING SYSTEMS AND METHOD FOR THE PRODUCTION OF A RADIATION-COATED COATING|

---

US5081308A|1988-12-15|1992-01-14|Ici Americas Inc.|Ultraviolet radiation absorbing compositions of bis-1,3-diketone derivatives of cyclohexane|

---

JPH03115267A|1989-09-28|1991-05-16|Maruho Kk|Propiophenone derivative, its production and central muscle relaxant and antispasmodic agent containing the same|

---

US4987159A|1990-04-11|1991-01-22|Fratelli Lamberti S.P.A.|Carbonyl derivatives of 1-phenylindan suitable for use as polymerization photoinitiators, their preparation and use|

---

DE4022234A1|1990-07-12|1992-01-16|Herberts Gmbh|METHOD FOR THE PRODUCTION OF PROTECTIVE, AUXILIARY AND INSULATING MATERIALS ON A FIBER BASE, FOR ELECTRICAL PURPOSES AND OPTICAL LADDER USING IMPREGNABLE DIMENSIONS THAT ARE CURRENT BY ENERGY RADIATION|

---

JPH0453573U|1990-09-10|1992-05-07|

---

US5160868A|1990-10-19|1992-11-03|Yang Tai Her|Adjustable brush ac/dc servo motor|

---

US5262232A|1992-01-22|1993-11-16|Minnesota Mining And Manufacturing Company|Vibration damping constructions using acrylate-containing damping materials|

---

US5252694A|1992-01-22|1993-10-12|Minnesota Mining And Manufacturing Company|Energy-polymerization adhesive, coating, film and process for making the same|

---

US6492413B2|1993-01-15|2002-12-10|G.D. Searle & Co.|3.4-diaryl thiophenes and analogs thereof having use as antiinflammatory agents|

---

DE4302123A1|1993-01-27|1994-07-28|Herberts Gmbh|Printing glass hollow-ware esp. bottle with ink contg. organic binder|

---

DK0693002T3†|1993-04-01|1998-06-02|Ppg Industries Inc|Means and methods for producing radiation-curable high-gloss coatings|

---

WO1994029355A1|1993-06-04|1994-12-22|Henkel Corporation|Citral acetal ethers of alpha-hydroxy phenyl ketones and polymerizable compositions|

---

US5474995A|1993-06-24|1995-12-12|Merck Frosst Canada, Inc.|Phenyl heterocycles as cox-2 inhibitors|

---

US5773182A|1993-08-05|1998-06-30|Kimberly-Clark Worldwide, Inc.|Method of light stabilizing a colorant|

---

US5643356A|1993-08-05|1997-07-01|Kimberly-Clark Corporation|Ink for ink jet printers|

---

US5645964A|1993-08-05|1997-07-08|Kimberly-Clark Corporation|Digital information recording media and method of using same|

---

CA2120838A1|1993-08-05|1995-02-06|Ronald Sinclair Nohr|Solid colored composition mutable by ultraviolet radiation|

---

US6211383B1|1993-08-05|2001-04-03|Kimberly-Clark Worldwide, Inc.|Nohr-McDonald elimination reaction|

---

US6017471A|1993-08-05|2000-01-25|Kimberly-Clark Worldwide, Inc.|Colorants and colorant modifiers|

---

US5700850A|1993-08-05|1997-12-23|Kimberly-Clark Worldwide|Colorant compositions and colorant stabilizers|

---

US5721287A|1993-08-05|1998-02-24|Kimberly-Clark Worldwide, Inc.|Method of mutating a colorant by irradiation|

---

US5733693A|1993-08-05|1998-03-31|Kimberly-Clark Worldwide, Inc.|Method for improving the readability of data processing forms|

---

US5865471A|1993-08-05|1999-02-02|Kimberly-Clark Worldwide, Inc.|Photo-erasable data processing forms|

---

US5514214A|1993-09-20|1996-05-07|Q2100, Inc.|Eyeglass lens and mold spin coater|

---

US5685754A|1994-06-30|1997-11-11|Kimberly-Clark Corporation|Method of generating a reactive species and polymer coating applications therefor|

---

US6071979A|1994-06-30|2000-06-06|Kimberly-Clark Worldwide, Inc.|Photoreactor composition method of generating a reactive species and applications therefor|

---

US6242057B1|1994-06-30|2001-06-05|Kimberly-Clark Worldwide, Inc.|Photoreactor composition and applications therefor|

---

US6008268A|1994-10-21|1999-12-28|Kimberly-Clark Worldwide, Inc.|Photoreactor composition, method of generating a reactive species, and applications therefor|

---

US6017661A|1994-11-09|2000-01-25|Kimberly-Clark Corporation|Temporary marking using photoerasable colorants|

---

JP3442176B2|1995-02-10|2003-09-02|富士写真フイルム株式会社|Photopolymerizable composition|

---

US5849411A|1995-06-05|1998-12-15|Kimberly-Clark Worldwide, Inc.|Polymer film, nonwoven web and fibers containing a photoreactor composition|

---

US5811199A|1995-06-05|1998-09-22|Kimberly-Clark Worldwide, Inc.|Adhesive compositions containing a photoreactor composition|

---

US5681380A|1995-06-05|1997-10-28|Kimberly-Clark Worldwide, Inc.|Ink for ink jet printers|

---

US5786132A|1995-06-05|1998-07-28|Kimberly-Clark Corporation|Pre-dyes, mutable dye compositions, and methods of developing a color|

---

US5747550A|1995-06-05|1998-05-05|Kimberly-Clark Worldwide, Inc.|Method of generating a reactive species and polymerizing an unsaturated polymerizable material|

---

US5739175A|1995-06-05|1998-04-14|Kimberly-Clark Worldwide, Inc.|Photoreactor composition containing an arylketoalkene wavelength-specific sensitizer|

---

US5798015A|1995-06-05|1998-08-25|Kimberly-Clark Worldwide, Inc.|Method of laminating a structure with adhesive containing a photoreactor composition|

---

EP0830638B1|1995-06-05|2000-08-23|Kimberly-Clark Worldwide, Inc.|Pre-dyes and compositions comprising them|

---

AT206150T|1995-06-28|2001-10-15|Kimberly Clark Co|DYE-STABILIZED COMPOSITIONS|

---

EP0850253B1|1995-09-11|1999-12-01|LAMBERTI S.p.A.|Betaketosulfonic derivatives suitable to the use as polymerization photoinitiators and photopolymerizable systems containing the same|

---

ES2175168T3|1995-11-28|2002-11-16|Kimberly Clark Co|COLOR COMPOUNDS STABILIZED BY LIGHT.|

---

DE19546899C1|1995-12-15|1997-01-09|Herberts Gmbh|Coating agent and use of the coating agent|

---

US5891229A|1996-03-29|1999-04-06|Kimberly-Clark Worldwide, Inc.|Colorant stabilizers|

---

US5855655A|1996-03-29|1999-01-05|Kimberly-Clark Worldwide, Inc.|Colorant stabilizers|

---

US5782963A|1996-03-29|1998-07-21|Kimberly-Clark Worldwide, Inc.|Colorant stabilizers|

---

US6099628A|1996-03-29|2000-08-08|Kimberly-Clark Worldwide, Inc.|Colorant stabilizers|

---

US6022498A|1996-04-19|2000-02-08|Q2100, Inc.|Methods for eyeglass lens curing using ultraviolet light|

---

US6280171B1|1996-06-14|2001-08-28|Q2100, Inc.|El apparatus for eyeglass lens curing using ultraviolet light|

---

US5712401A|1996-04-29|1998-01-27|First Chemical Corporation|Processes for preparing thioxanthone and derivatives thereof|

---

SG53043A1|1996-08-28|1998-09-28|Ciba Geigy Ag|Molecular complex compounds as photoinitiators|

---

DE19635447C1|1996-08-31|1997-11-20|Herberts Gmbh|Multilayer repair painting process, especially for car repairs|

---

US6287749B1|1997-05-05|2001-09-11|First Chemical Corporation|Biradical photoinitiators and photopolymerizable compositions|

---

US5989462A|1997-07-31|1999-11-23|Q2100, Inc.|Method and composition for producing ultraviolent blocking lenses|

---

US6524379B2|1997-08-15|2003-02-25|Kimberly-Clark Worldwide, Inc.|Colorants, colorant stabilizers, ink compositions, and improved methods of making the same|

---

US6150420A|1998-06-01|2000-11-21|Theramax, Inc.|Method for enhanced brain delivery of bupropion|

---

WO1999062962A1|1998-06-03|1999-12-09|Kimberly-Clark Worldwide, Inc.|Novel photoinitiators and applications therefor|

---

JP2002517540A|1998-06-03|2002-06-18|キンバリークラークワールドワイドインコーポレイテッド|Neo nanoplast and microemulsion technology for ink and ink jet printing|

---

US6228157B1|1998-07-20|2001-05-08|Ronald S. Nohr|Ink jet ink compositions|

---

US6416307B1|1998-09-25|2002-07-09|Q2100, Inc.|Plastic lens systems, compositions, and methods|

---

EP1117698B1|1998-09-28|2006-04-19|Kimberly-Clark Worldwide, Inc.|Chelates comprising chinoid groups as photoinitiators|

---

CA2347768A1|1998-10-27|2000-05-04|Edward J. J. Grabowski|Synthesis of methylthiophenyl hydroxyketones|

---

EP1140761B1|1999-01-12|2003-10-08|Clariant FinanceLimited|Benzophenones and the use thereof as photoinitiators|

---

ES2195869T3|1999-01-19|2003-12-16|Kimberly Clark Co|NEW COLORS, COLOR STABILIZERS, INK COMPOUNDS AND IMPROVED METHODS FOR MANUFACTURING.|

---

US6331056B1|1999-02-25|2001-12-18|Kimberly-Clark Worldwide, Inc.|Printing apparatus and applications therefor|

---

US6419873B1|1999-03-19|2002-07-16|Q2100, Inc.|Plastic lens systems, compositions, and methods|

---

US6294698B1|1999-04-16|2001-09-25|Kimberly-Clark Worldwide, Inc.|Photoinitiators and applications therefor|

---

US6368395B1|1999-05-24|2002-04-09|Kimberly-Clark Worldwide, Inc.|Subphthalocyanine colorants, ink compositions, and method of making the same|

---

US6698708B1|2000-03-30|2004-03-02|Q2100, Inc.|Gasket and mold assembly for producing plastic lenses|

---

US6723260B1|2000-03-30|2004-04-20|Q2100, Inc.|Method for marking a plastic eyeglass lens using a mold assembly holder|

---

US6960312B2|2000-03-30|2005-11-01|Q2100, Inc.|Methods for the production of plastic lenses|

---

US6716375B1|2000-03-30|2004-04-06|Q2100, Inc.|Apparatus and method for heating a polymerizable composition|

---

US6632535B1|2000-06-08|2003-10-14|Q2100, Inc.|Method of forming antireflective coatings|

---

WO2002000735A1|2000-06-19|2002-01-03|Kimberly-Clark Worldwide, Inc.|Novel photoinitiators and applications therefor|

---

EP1341823B1|2000-12-13|2008-10-01|Ciba Holding Inc.|Surface-active photoinitiators|

---

US6808381B2|2001-02-20|2004-10-26|Q2100, Inc.|Apparatus for preparing an eyeglass lens having a controller|

---

US6712331B2|2001-02-20|2004-03-30|Q2100, Inc.|Holder for mold assemblies with indicia|

---

US6899831B1|2001-02-20|2005-05-31|Q2100, Inc.|Method of preparing an eyeglass lens by delayed entry of mold assemblies into a curing apparatus|

---

US7139636B2|2001-02-20|2006-11-21|Q2100, Inc.|System for preparing eyeglass lenses with bar code reader|

---

US6612828B2|2001-02-20|2003-09-02|Q2100, Inc.|Fill system with controller for monitoring use|

---

US7004740B2|2001-02-20|2006-02-28|Q2100, Inc.|Apparatus for preparing an eyeglass lens having a heating system|

---

US6726463B2|2001-02-20|2004-04-27|Q2100, Inc.|Apparatus for preparing an eyeglass lens having a dual computer system controller|

---

US7124995B2|2001-02-20|2006-10-24|Q2100, Inc.|Holder for mold assemblies and molds|

---

US6655946B2|2001-02-20|2003-12-02|Q2100, Inc.|Apparatus for preparing an eyeglass lens having a controller for conveyor and curing units|

---

US6752613B2|2001-02-20|2004-06-22|Q2100, Inc.|Apparatus for preparing an eyeglass lens having a controller for initiation of lens curing|

---

US7074352B2|2001-02-20|2006-07-11|Q2100, Inc.|Graphical interface for monitoring usage of components of a lens forming apparatus|

---

US6758663B2|2001-02-20|2004-07-06|Q2100, Inc.|System for preparing eyeglass lenses with a high volume curing unit|

---

US6790024B2|2001-02-20|2004-09-14|Q2100, Inc.|Apparatus for preparing an eyeglass lens having multiple conveyor systems|

---

US6962669B2|2001-02-20|2005-11-08|Q2100, Inc.|Computerized controller for an eyeglass lens curing apparatus|

---

US6676399B1|2001-02-20|2004-01-13|Q2100, Inc.|Apparatus for preparing an eyeglass lens having sensors for tracking mold assemblies|

---

US7037449B2|2001-02-20|2006-05-02|Q2100, Inc.|Method for automatically shutting down a lens forming apparatus|

---

US6840752B2|2001-02-20|2005-01-11|Q2100, Inc.|Apparatus for preparing multiple eyeglass lenses|

---

US6790022B1|2001-02-20|2004-09-14|Q2100, Inc.|Apparatus for preparing an eyeglass lens having a movable lamp mount|

---

US7052262B2|2001-02-20|2006-05-30|Q2100, Inc.|System for preparing eyeglasses lens with filling station|

---

US6676398B2|2001-02-20|2004-01-13|Q2100, Inc.|Apparatus for preparing an eyeglass lens having a prescription reader|

---

US6863518B2|2001-02-20|2005-03-08|Q2100, Inc.|Mold filing apparatus having multiple fill stations|

---

US7051290B2|2001-02-20|2006-05-23|Q2100, Inc.|Graphical interface for receiving eyeglass prescription information|

---

US7083404B2|2001-02-20|2006-08-01|Q2100, Inc.|System for preparing an eyeglass lens using a mold holder|

---

US7025910B2|2001-02-20|2006-04-11|Q2100, Inc|Method of entering prescription information|

---

US6875005B2|2001-02-20|2005-04-05|Q1200, Inc.|Apparatus for preparing an eyeglass lens having a gating device|

---

US6893245B2|2001-02-20|2005-05-17|Q2100, Inc.|Apparatus for preparing an eyeglass lens having a computer system controller|

---

US6702564B2|2001-02-20|2004-03-09|Q2100, Inc.|System for preparing an eyeglass lens using colored mold holders|

---

US7045081B2|2001-02-20|2006-05-16|Q2100, Inc.|Method of monitoring components of a lens forming apparatus|

---

US6709257B2|2001-02-20|2004-03-23|Q2100, Inc.|Eyeglass lens forming apparatus with sensor|

---

US7060208B2|2001-02-20|2006-06-13|Q2100, Inc.|Method of preparing an eyeglass lens with a controller|

---

US7011773B2|2001-02-20|2006-03-14|Q2100, Inc.|Graphical interface to display mold assembly position in a lens forming apparatus|

---

ITMI20010733A1|2001-04-05|2002-10-07|Recordati Chem Pharm|USE OF ISOENZIN COX-2 INHIBITORS FOR THE TREATMENT OF URINARY INCONTINENCE|

---

GB0118936D0|2001-08-02|2001-09-26|Unilever Plc|Improvements relating to colour-safe fabric treatment compositions|

---

TWI312786B|2001-11-08|2009-08-01|Ciba Sc Holding Ag|Novel difunctional photoinitiators|

---

AU2002359715A1|2001-12-19|2003-07-09|The University Of Texas Health Science Center At San Antonio|Implant coatings|

---

GB0205276D0|2002-03-06|2002-04-17|Unilever Plc|Bleaching composition|

---

US7044429B1|2002-03-15|2006-05-16|Q2100, Inc.|Methods and systems for coating eyeglass lens molds|

---

US6464484B1|2002-03-30|2002-10-15|Q2100, Inc.|Apparatus and system for the production of plastic lenses|

---

US20030225179A1|2002-04-26|2003-12-04|Chiu Chingfan Chris|Novel morpholinoketone derivatives, and preparation process and uses of the same|

---

JP2004043433A|2002-04-26|2004-02-12|Kitai Kagi Kofun Yugenkoshi|Morpholinoketone derivative and its use|

---

AU2003246675A1|2002-07-19|2004-02-09|Ciba Specialty Chemicals Holding Inc.|New difunctional photoinitiators|

---

MXPA05010951A|2003-04-16|2005-11-25|Ciba Sc Holding Ag|Radiation curable ink-jet ink containing an alpha hydroxy ketone as photoinitiator.|

---

MXPA05011543A|2003-05-06|2005-12-14|Ciba Sc Holding Ag|Novel trifunctional photoinitiators.|

---

JP4291638B2|2003-07-29|2009-07-08|富士フイルム株式会社|Alkali-soluble polymer and planographic printing plate precursor using the same|

---

ITVA20030028A1|2003-08-07|2005-02-08|Lamberti Spa|TRANSPARENT PHOTOPOLYMIZED SYSTEMS FOR THE PREPARATION OF HIGH THICKNESS COATINGS.|

---

JP4348253B2|2003-08-20|2009-10-21|富士フイルム株式会社|Conductive pattern material and method of forming conductive pattern|

---

ITVA20030040A1|2003-10-27|2005-04-28|Lamberti Spa|WHITE SOLID PHOTOINIZER FOR POWDER AND PROCEDURE FOR ITS PREPARATION.|

---

EP1711862B1|2004-02-02|2014-09-10|Basf Se|Functionalized photoinitiators|

---

JP3968089B2|2004-05-25|2007-08-29|シャープ株式会社|Electrophotographic photosensitive member and image forming apparatus having the same|

---

EP1930309B1|2004-07-08|2009-10-21|Basf Se|Preparation of alpha-hydroxyketones|

---

JP5089866B2|2004-09-10|2012-12-05|富士フイルム株式会社|Planographic printing method|

---

DE602005008626D1|2004-09-29|2008-09-11|Ciba Holding Inc|PROCESS FOR PREPARING AROMATIC THIOPHENYL KETONE|

---

WO2006046698A1|2004-10-29|2006-05-04|Dainippon Ink And Chemicals, Inc.|Active energy ray-curable inkjet recording ink|

---

JP4967378B2|2005-03-29|2012-07-04|セイコーエプソン株式会社|Ink composition|

---

JP2006276640A|2005-03-30|2006-10-12|Taiyo Ink Mfg Ltd|Photosensitive paste and burned product pattern obtained using same|

---

JP4474317B2|2005-03-31|2010-06-02|富士フイルム株式会社|Preparation method of lithographic printing plate|

---

ITVA20050032A1|2005-05-13|2006-11-14|Lamberti Spa|FENYLLOGOXYL ESTERS GENERATING RESIDUAL LOW MIGRABILITY AND ODOR|

---

JP2006335826A|2005-05-31|2006-12-14|Fujifilm Holdings Corp|Ink composition for inkjet recording and method for manufacturing planographic printing plate using the same|

---

NZ561375A|2005-06-27|2011-06-30|Biovail Lab Int Srl|Bupropion hydrobromide, and crystalline forms, compositions, and uses of this compound|

---

JP4317853B2|2006-01-12|2009-08-19|シャープ株式会社|Electrophotographic photosensitive member, method for producing the same, and image forming apparatus using the same|

---

JP5276264B2|2006-07-03|2013-08-28|富士フイルム株式会社|INK COMPOSITION, INKJET RECORDING METHOD, PRINTED MATERIAL, AND METHOD FOR PRODUCING A lithographic printing plate|

---

EP1927633A1|2006-11-30|2008-06-04|Seiko Epson Corporation|Ink composition, two-pack curing ink composition set, and recording method and recorded matter using these|

---

US7985785B2|2007-01-15|2011-07-26|Fujifilm Corporation|Ink composition and inkjet recording method using the same|

---

JP5472670B2|2007-01-29|2014-04-16|セイコーエプソン株式会社|Ink set, ink jet recording method and recorded matter|

---

US8541063B2|2007-02-06|2013-09-24|Fujifilm Corporation|Undercoat solution, ink-jet recording method and ink-jet recording device|

---

US8240808B2|2007-02-07|2012-08-14|Fujifilm Corporation|Ink-jet head maintenance device, ink-jet recording device and ink-jet head maintenance method|

---

JP5227521B2|2007-02-26|2013-07-03|富士フイルム株式会社|Ink composition, ink jet recording method, printed matter, and ink set|

---

JP5224699B2|2007-03-01|2013-07-03|富士フイルム株式会社|Ink composition, inkjet recording method, printed material, method for producing lithographic printing plate, and lithographic printing plate|

---

US8894197B2|2007-03-01|2014-11-25|Seiko Epson Corporation|Ink set, ink-jet recording method, and recorded material|

---

JP5098397B2|2007-03-29|2012-12-12|コニカミノルタホールディングス株式会社|Ink jet ink and ink jet recording method|

---

JP5243072B2|2007-03-30|2013-07-24|富士フイルム株式会社|Ink composition, and image recording method and image recorded material using the same|

---

JP4601009B2|2007-03-30|2010-12-22|富士フイルム株式会社|Ink set for inkjet recording and inkjet recording method|

---

JP5306681B2|2007-03-30|2013-10-02|富士フイルム株式会社|Polymerizable compound, polymer, ink composition, printed matter, and inkjet recording method|

---

WO2008122504A1|2007-04-04|2008-10-16|Basf Se|Alpha-hydroxyketones|

---

EP2028241A1|2007-08-09|2009-02-25|Seiko Epson Corporation|Photocurable ink composition, ink cartridge, inkjet recording method and recorded matter|

---

JP4816976B2|2007-08-09|2011-11-16|セイコーエプソン株式会社|Photocurable ink composition|

---

EP2048539A1|2007-09-06|2009-04-15|FUJIFILM Corporation|Processed pigment, pigment-dispersed composition, colored photosensitive composition, color filter, liquid crystal display element, and solid image pickup element|

---

JP4766281B2|2007-09-18|2011-09-07|セイコーエプソン株式会社|Non-aqueous ink composition for ink jet recording, ink jet recording method and recorded matter|

---

JP5255369B2|2007-09-25|2013-08-07|富士フイルム株式会社|Photocurable coating composition, overprint and method for producing the same|

---

US9442372B2|2007-09-26|2016-09-13|Fujifilm Corporation|Pigment dispersion composition, photocurable composition and color filter|

---

EP2053095B2|2007-09-28|2017-02-22|FUJIFILM Corporation|Ink composition and inkjet recording method using the same|

---

JP4898618B2|2007-09-28|2012-03-21|富士フイルム株式会社|Inkjet recording method|

---

JP5227560B2|2007-09-28|2013-07-03|富士フイルム株式会社|Ink composition, inkjet recording method, printed matter, and method for producing molded printed matter|

---

JP5265165B2|2007-09-28|2013-08-14|富士フイルム株式会社|Coating apparatus and ink jet recording apparatus using the same|

---

EP2218756B1|2007-11-01|2013-07-31|FUJIFILM Corporation|Pigment dispersion composition, curable color composition, color filter and method for producing the same|

---

GB0724863D0|2007-12-21|2008-01-30|Unilever Plc|Fabric treatment active|

---

JP5457636B2|2008-01-22|2014-04-02|富士フイルム株式会社|Photocurable composition, photocurable ink composition, method for producing photocured product, and inkjet recording method|

---

JP5254632B2|2008-02-07|2013-08-07|富士フイルム株式会社|Ink composition, inkjet recording method, printed matter, and molded printed matter|

---

JP5147499B2|2008-02-13|2013-02-20|富士フイルム株式会社|Photosensitive coloring composition, color filter and method for producing the same|

---

US20090214797A1|2008-02-25|2009-08-27|Fujifilm Corporation|Inkjet ink composition, and inkjet recording method and printed material employing same|

---

JP2009269397A|2008-02-29|2009-11-19|Seiko Epson Corp|Method of forming opaque layer, recording method, ink set, ink cartridge, and recording apparatus|

---

JP5583329B2|2008-03-11|2014-09-03|富士フイルム株式会社|Pigment composition, ink composition, printed matter, inkjet recording method, and polyallylamine derivative|

---

KR101654666B1|2008-03-17|2016-09-06|후지필름 가부시키가이샤|Pigment-dispersed composition, colored photosensitive composition, photocurable composition, color filter, liquid crystal display element, and solid image pickup element|

---

JP4914862B2|2008-03-26|2012-04-11|富士フイルム株式会社|Inkjet recording method and inkjet recording apparatus|

---

JP5155920B2|2008-03-31|2013-03-06|富士フイルム株式会社|Photosensitive transparent resin composition, method for producing color filter, and color filter|

---

JP5414367B2|2008-06-02|2014-02-12|富士フイルム株式会社|Pigment dispersion and ink composition using the same|

---

US9624171B2|2008-06-06|2017-04-18|Basf Se|Photoinitiator mixtures|

---

JP5441369B2|2008-07-16|2014-03-12|富士フイルム株式会社|Photocurable composition, ink composition, and ink jet recording method using the same|

---

JP2010024277A|2008-07-16|2010-02-04|Fujifilm Corp|Inkjet printing ink composition and inkjet recording method|

---

JP5106285B2|2008-07-16|2012-12-26|富士フイルム株式会社|Photocurable composition, ink composition, and ink jet recording method using the ink composition|

---

JP5258428B2|2008-07-16|2013-08-07|富士フイルム株式会社|Aqueous ink composition, aqueous ink composition for inkjet recording, and inkjet recording method|

---

JP5383133B2|2008-09-19|2014-01-08|富士フイルム株式会社|Ink composition, ink jet recording method, and method for producing printed product|

---

JP2010077228A|2008-09-25|2010-04-08|Fujifilm Corp|Ink composition, inkjet recording method and printed material|

---

JP5623416B2|2008-11-03|2014-11-12|ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ|Photoinitiator mixture|

---

JP5344892B2|2008-11-27|2013-11-20|富士フイルム株式会社|Ink jet ink composition and ink jet recording method|

---

JP2010180330A|2009-02-05|2010-08-19|Fujifilm Corp|Non-aqueous ink, ink set, method for recording image, device for recording image, and recorded matter|

---

JP5350827B2|2009-02-09|2013-11-27|富士フイルム株式会社|Ink composition and inkjet recording method|

---

JP5340198B2|2009-02-26|2013-11-13|富士フイルム株式会社|Dispersion composition|

---

JP2010209183A|2009-03-09|2010-09-24|Fujifilm Corp|Ink composition and ink-jet recording method|

---

JP5349095B2|2009-03-17|2013-11-20|富士フイルム株式会社|Ink composition and inkjet recording method|

---

JP5349097B2|2009-03-19|2013-11-20|富士フイルム株式会社|Ink composition, inkjet recording method, printed matter, and method for producing molded printed matter|

---

JP5383289B2|2009-03-31|2014-01-08|富士フイルム株式会社|Ink composition, ink composition for inkjet, inkjet recording method, and printed matter by inkjet method|

---

JP5657267B2|2009-04-16|2015-01-21|富士フイルム株式会社|Polymerizable composition for color filter, color filter, and solid-state imaging device|

---

CN101923282B|2009-06-09|2012-01-25|清华大学|Nano-imprint resist and nano-imprint method adopting same|

---

CA2769210A1|2009-06-29|2011-01-06|Dic Corporation|Michael addition reaction product and active energy ray-curable composition|

---

JP5572026B2|2009-09-18|2014-08-13|富士フイルム株式会社|Ink composition and inkjet recording method|

---

JP5530141B2|2009-09-29|2014-06-25|富士フイルム株式会社|Ink composition and inkjet recording method|

---

JP5692490B2|2010-01-28|2015-04-01|セイコーエプソン株式会社|Aqueous ink composition, ink jet recording method and recorded matter|

---

JP2011152747A|2010-01-28|2011-08-11|Seiko Epson Corp|Aqueous ink composition, inkjet recording method, and recorded matter|

---

JP5554114B2|2010-03-29|2014-07-23|富士フイルム株式会社|Actinic radiation curable ink composition for inkjet, printed matter, printed matter production method, printed matter molded product, and printed matter molded product|

---

EP2371912B1|2010-03-31|2014-04-30|Fujifilm Corporation|Active radiation curable ink composition, ink composition for inkjet recording, printed matter, and method of producing molded article of printed matter|

---

JP2012031388A|2010-05-19|2012-02-16|Fujifilm Corp|Printing method, method for preparing overprint, method for processing laminate, light-emitting diode curable coating composition, and light-emitting diode curable ink composition|

---

CN102958909B|2010-06-28|2016-11-09|巴斯夫欧洲公司|Metal-free bleaching composition|

---

JP5606817B2|2010-07-27|2014-10-15|富士フイルム株式会社|Actinic radiation curable inkjet ink composition, printed material, printed material molded body, and method for producing printed material|

---

EP2423277A3|2010-08-27|2012-05-09|Fujifilm Corporation|Ink composition for inkjet recording, inkjet recording method and inkjet printed article|

---

CN103601628B|2010-11-12|2015-11-18|深圳市有为化学技术有限公司|Contraposition or position functionalization aromatic ketone compounds, its preparation method and Photoepolymerizationinitiater initiater thereof|

---

US8816211B2|2011-02-14|2014-08-26|Eastman Kodak Company|Articles with photocurable and photocured compositions|

---

US20120208914A1|2011-02-14|2012-08-16|Deepak Shukla|Photoinitiator compositions and uses|

---

US20120207935A1|2011-02-14|2012-08-16|Deepak Shukla|Photocurable inks and methods of use|

---

CN103391979A|2011-02-28|2013-11-13|富士胶片株式会社|Ink composition, image forming method and printed material|

---

JP2012201874A|2011-03-28|2012-10-22|Fujifilm Corp|Ink composition, and method of forming image|

---

JP5300904B2|2011-03-31|2013-09-25|富士フイルム株式会社|Ink composition and image forming method|

---

JP5764416B2|2011-07-08|2015-08-19|富士フイルム株式会社|Ink composition and image forming method|

---

JP5756071B2|2011-09-29|2015-07-29|富士フイルム株式会社|Inkjet ink composition and inkjet recording method|

---

CN102504054B|2011-11-01|2014-07-02|长沙新宇高分子科技有限公司|Hydroxy-ketone photoinitiator containing multiple functional groups for reducing and eliminating VOCemission|

---

US9353214B2|2011-12-16|2016-05-31|The University Of Akron|Substituted phenacyl molecules and photoresponsive polymers|

---

EP2644664B1|2012-03-29|2015-07-29|Fujifilm Corporation|Actinic radiation-curing type ink composition, inkjet recording method, decorative sheet, decorative sheet molded product, process for producing in-mold molded article, and in-mold molded article|

---

JP5606567B2|2012-04-19|2014-10-15|富士フイルム株式会社|Actinic ray curable ink composition, ink jet recording method, decorative sheet, decorative sheet molded product, in-mold molded product manufacturing method, and in-mold molded product|

---

EP2896636B1|2012-09-14|2017-09-27|FUJIFILM Corporation|Curable composition and image-forming method|

---

ES2655681T3|2012-09-28|2018-02-21|Fujifilm Corporation|Functional polymeric membrane and method for its production|

---

CN104703682B|2012-09-28|2016-05-18|富士胶片株式会社|High molecular functional film and manufacture method thereof|

---

JP6053942B2|2012-10-19|2016-12-27|ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ|Hybrid photoinitiator|

---

CN103012317B|2012-12-23|2014-10-15|惠州市华泓新材料有限公司|Alkyl phenyl derivative and application of alkyl phenyl derivative as photoinitiator|

---

JP6126498B2|2013-02-15|2017-05-10|富士フイルム株式会社|Polymer functional membrane and method for producing the same|

---

ES2731827T3|2013-03-07|2019-11-19|Fujifilm Corp|Functional polymeric membrane and its manufacturing method|

---

JP5980702B2|2013-03-07|2016-08-31|富士フイルム株式会社|INKJET INK COMPOSITION, INKJET RECORDING METHOD, AND MOLDED PRINTED PRODUCTION METHOD|

---

JP6004971B2|2013-03-12|2016-10-12|富士フイルム株式会社|Inkjet ink composition for producing decorative sheet molded product or in-mold molded product, inkjet recording method for producing decorated sheet molded product or in-mold molded product, ink set for producing decorative sheet molded product or in-mold molded product, decorative Decorative sheet for producing sheet molded product or in-mold molded product, decorated sheet molded product, and method for producing in-mold molded product|

---

JP5939644B2|2013-08-30|2016-06-22|富士フイルム株式会社|Image forming method, in-mold molded product manufacturing method, and ink set|

---

CN103709036B|2013-12-03|2015-07-29|天津久日化学股份有限公司|Bifunctional Benzoyl Formic Acid hydroxyketone ester compound and the light trigger containing this compounds|

---

WO2015140541A1|2014-03-20|2015-09-24|Fujifilm Speciality Ink Systems Limited|Printing ink|

---

JP6066960B2|2014-05-30|2017-01-25|富士フイルム株式会社|Actinic ray curable ink composition for molding process, ink set, inkjet recording method, decorative sheet for molding process, decorative sheet molded product, and method for producing in-mold molded product|

---

CN106470971B|2014-08-01|2020-03-03|株式会社艾迪科|Novel polymerization initiator and radical polymerizable composition containing the same|

---

CN104151267B|2014-08-08|2016-04-27|广东鑫钰新材料股份有限公司|The preparation method of the cyclosubstituted 1-hydroxy cyclohexyl phenylketone of nitrogen-containing hetero on aryl|

---

WO2016034963A1|2014-09-04|2016-03-10|Basf Se|Polycyclic photoinitiators|

---

AU2016311962B2|2015-08-27|2018-11-15|Fujifilm Corporation|Photosensitive composition, image forming method, film forming method, resin, image, and film|

---

EP3412694B1|2016-02-05|2021-12-08|FUJIFILM Corporation|Aqueous dispersion, method for manufacturing the same, and image forming method|

---

CN108603024B|2016-02-05|2021-06-08|富士胶片株式会社|Water dispersion, method for producing same, and image forming method|

---

WO2017135088A1|2016-02-05|2017-08-10|富士フイルム株式会社|Aqueous dispersion, production method therefor, and image formation method|

---

WO2017138434A1|2016-02-10|2017-08-17|富士フイルム株式会社|Inkjet recording method|

---

EP3575372A4|2017-01-30|2020-05-06|FUJIFILM Corporation|Active-ray-curable ink composition and inkjet recording method|

---

JP6742502B2|2017-02-24|2020-08-19|富士フイルム株式会社|Photocurable ink composition and image forming method|

---

EP3587512A4|2017-02-24|2020-03-04|FUJIFILM Corporation|Photocurable ink composition and image forming method|

---

EP3604458B1|2017-03-30|2021-05-05|FUJIFILM Corporation|Photocurable ink composition and image formation method|

---

EP3608375A4|2017-04-03|2020-04-15|FUJIFILM Corporation|Ink composition, production method therefor, and image formation method|

---

JP6900466B2|2017-04-03|2021-07-07|富士フイルム株式会社|Ink composition, its manufacturing method, and image forming method|

---

ES2867807T3|2017-04-24|2021-10-20|Igm Group B V|Process for the preparation of α-functionalized ketones|

---

WO2018198993A1|2017-04-26|2018-11-01|富士フイルム株式会社|Photo-curable ink composition and image forming method|

---

JP6861811B2|2017-06-20|2021-04-21|富士フイルム株式会社|Photocurable ink composition and image forming method|

---

EP3660111A4|2017-07-26|2020-07-22|FUJIFILM Corporation|Ink composition, method for producing same, and image formation method|

---

JP6820429B2|2017-08-29|2021-01-27|富士フイルム株式会社|Ink composition, its manufacturing method, and image forming method|

---

WO2019064979A1|2017-09-27|2019-04-04|富士フイルム株式会社|Actinic-ray-curable ink-jet ink, light-shielding film, and production method for light-shielding film|

---

WO2019188481A1|2018-03-27|2019-10-03|富士フイルム株式会社|Photocurable ink composition and image forming method|

---

EP3778791A4|2018-03-27|2021-05-19|FUJIFILM Corporation|Photocurable ink composition and image forming method|

---

GB201815405D0|2018-09-21|2018-11-07|Fujifilm Mfg Europe Bv|Membranes suitable for detecting, filtering and/or purifying biomolecules|

---

GB201815407D0|2018-09-21|2018-11-07|Fujifilm Mfg Europe Bv|Membranes suitable for detecting, filtering and/or purifying biomolecules and metal-ions|

---

EP3902878A1|2018-12-28|2021-11-03|IGM Resins Italia S.r.l.|Photoinitiators|

---

EP3936579A1|2019-03-06|2022-01-12|FUJIFILM Corporation|Ink-jet ink composition, method for recording image, and object with recorded image|

---

EP3950856A1|2019-03-29|2022-02-09|FUJIFILM Corporation|Photocurable ink composition and method for image recording|

---

GB201904581D0|2019-04-02|2019-05-15|Fujifilm Mfg Europe Bv|Membranes and processes for their preparation|

---

GB201917710D0|2019-12-04|2020-01-15|Fujifilm Mfg Europe Bv|Affinity membranes, compounds, compositions and processes for their preparation and use|

---

GB201917711D0|2019-12-04|2020-01-15|Fujifilm Mfg Europe Bv|Affinity membranes, compounds, compositions and processes for their preparation and use|

---

GB202013838D0|2020-09-03|2020-10-21|Fujifilm Mfg Europe Bv|Composite membrane|

---

GB202019478D0|2020-12-10|2021-01-27|Fujifilm Corp|Purifying polar liquids|

---

GB202114000D0|2021-09-30|2021-11-17|Fujifilm Mfg Europe Bv|Membranes|

---

GB202113999D0|2021-09-30|2021-11-17|Fujifilm Mfg Europe Bv|Membranes|

法律状态:

优先权:

---

申请号 | 申请日 | 专利标题

---

CH1588477|1977-12-22|

---

CH251878|1978-03-08|

---

CH972378|1978-09-18|

---